Women of
             the
             Fur Trade
Natural Pigments      

  Natural Pigments              

   By Patsy Harper       

 

      For millenia, humans have beautified their world,
   adorned their bodies and clothing, deccorated their 
   dwellings, and expressed their thoughts by painting.
   Pigments are the basis of all paints, and have come
   from natural sources from the beginning of time
   through today.

 

     The focus of this project is to determine sources of
   Natural paigments and binders used prior to 1840,
   with methods and recipes for their use on a variety of
   surfaces, with an emphahsis on painting on buckskin
   and rawhide. 
 

      Paint in it's simplest form, consists of ground up
   pigment suspended in some sort of liquid, or binder.
   When the liquid dries into a film, the ground pigment
   is mechanically bound or stuck to the painting surface.
   Dyes on the other hand are chemically bound to a
   material generally with the use of a mordant (alum,
   chromium, copper, tin and iron.) This project will
   focus on ground mineral pigments, binders and
   application methods.

 

     The first paintings were Cave Paintings. Ancient
   peoples would decorate walls of protected Caves with
   paint made from dirt or charcoal mixed with spit or
   animal fat. In Cave paintings, the pigments (often
   carbon black or ochre) stick to the wall partially
   because the pigment gets trapped in the pourous wall,
   and partially because the binding media (the spit or
   fat) dries, adhering the pigment to the wall. Over the
   years, countless graves unearthed by archaeologists,
   exposed bodies covered in red pigment or chunks of
   pigment buried alongside the bodies. Red, associated
   with blood, the most life sustaining of body fluids, was
   the appropriate color to symbolize life's meaning and
   end. The word Hematite (the source of many iron oxide
   pigments) is derived from the Greek word "hema"
   meaning blood.

 

     The predominant colors used in rock art and cave art
   are black(from charcoal, soot, or manganese oxide),
   yellow ochre (limonite), red ochre (hematite or baked
   limonite), and white (kaolin clay, burnt shells, powdered
   gypsum, or powdered calcium carbonate). All of theses
   pigmeents may be used on leather or rawhide as well.
   Early cave art in Seminole Canyon was monochromatic,
   in red, and as culture grew more sophisticated, the color
   palette expanded.

 

     Many colors of pigments were obtained from both
   organic and inorganic sources in ancient times, and
   used to paint various surfaces such as braintan leather
   clothing and accoutrements, rawhide, the human body,
   etc. Blue color was obtained from powdered azurite
   and lapis, duck manure, and certain clays. A fine
   Blue-green clay was obtained from deposits near
   Mankato, Michigan. Organic sources of blue include
   Turkey's Tail, a greenish blue polypore that grows on
   dead decaying wood (not tannish ones). Native
   Americans could get Indigo from either Guatemala or
   Ecuador, which was traded well up onto Kansas, long
   before the Spanish ever set foot here. American Indigo
   has purple tones to it, but Indian-Japanese indigo has
   green tones. Berries and crushed flowers were also used
   to obtain blue color, by rubbing the plant material
   directly on the leather. Violets and Broadbeard
   Beardtongue (Penstemon angustifolius Nutt.ex Pursh)
   were examples of the flowers petals used for blue.

 

     During the reservation period in 1880's-1890's,
   laundry bluing was used as a replacement for
   organic blue pigments used by the Native Americans.
   It's main ingredient in the begining was powdered
   synthetic ultramarine. It was obtained in trade, came
   as a liquid or as a powder compressed into stick, and
   was used on many buckskin items, particularly by
   the Kiowa. Here are some examples of Kiowa
   artifacts from the National Museum of American
   History. 

           
               Kiowa women's moccasin stained with laundry bluing
                            Photograph by Paul Calcaterra
   
                         
                Kiowa men's moccasins stained with laudry bluing

                         
                                    Kiowa's men shirt front,
                            fringe stained with laundry bluing

                


                          
                Sample Swatch of bluing on commercial braintain,
                     left is undiluted,right is diluted with water,
                                       by Jack Smith

 

     An organic source of red was Cochineal. It was native
   west of the Mississippi, and is produced from the
   bodies of small insects that grow on the prickly pear
   cactus.

   Lady's Bedstraw gives a good vermillion red color.
   Harvest the roots, dry them out, clean the mud etc.
   off of them and then grind the roots really fine, then
   soak them to extract the red coloring. The key here is
   drying the root first. Blood was also used as red
   pigment. Pucoon roots also yield a red pigment.

 

     Powdered catlinite stone dust can be used as a pigment
   on buckskin as well. Just moisten the leather with spit
   first, then rub in the powdered stone pigment and let it
   dry. It produces a dark dusty pinkish red, as in the
   horse quirt below, made recently by Jack Smith of
   South Dakota.


      
  
               Catlinite dust was also used on the exposed rawhide on this
                 Crow-style knife sheath, also made by Jack Smith.
                          

 

     Grasses will produce green pigment, gathered fresh,
   wadded up and crushed, and rubbed directly onto the
   leather. Color varies with type of grass and water
   content. Other crushed leaves will produce green
   pigment as well, from the chlorophyll content in the
   leaf. Powdered malachite can be used as green pigment
   as well. Lambsquarter and pond algae can be used for
   greens. Yellows can be obtained from curly dock root
   and sumac root. Winged dock is a nice yellow orange.

 

     Walnut hulls, boiled or soaked in water, produce a
   dark brown stain that can be used to dye buckskin.
   Pecan hulls, processed the same way, produce a
   lighter golden brown stain. In Norman Feder's
   article on bottom tab leggings of the Sioux, he states
   that the brown paint used for stripes was made
   from powdered lignite. Lignite is a low-grade coal
   that can be found in many places in Eastern
   Montana, for example, in rocky outcroppings on
   erouded hillsides. It is a dark brown-black as it
   comes from the ground.

 

     Native Americans used yellow and red ochre
   extensively as stains on buckskins garments. Here
   is an example of Mescalero Apache woman's skirt
   stained with both, from American Museum of 
   Natural History: 
      
                
            A Kiowa dress with Cowrie shells and yellow ochre stain on
           the bodice,from Sotheby's 1998 auction catalog (Note green
                                pigment stain at the bottom hem)
  
                 

           Here is an outstanding Kiowa dress with green pigment stain,
                          yellow ochre, and red ochre at the bottom.

                                   

 

     Some of the first European and American artists to
   travel west used Natural pigments to paint a record
   of Native American tribes and their lives. Until paint
   was produced commercially during the Industrial
   Revolution (circa 1800), painters had to make their
   own paints by grinding pigment into oil. The paint
   would harden and would have to be made fresh each
   day. Due to the difficulty of transporting slow- drying
   wet oil paintings, many worked in watercolors or
   charcoal sketches in the field, and came home to make
   the oil paintings later from their field sketches. Often,
   they made their own pigments from available materials,
   mixing pigments with water and honey. The honey acts
   a humectant to keep the paint softer and more easily
   mixed, and to bind it to the paper.

 

     Binders in paint make pigment stick to the surface;
   similar to the way mordants make dyes stick to fabric
   surfaces. Various sealers may also be used after the
   pigment is applied. Sometimes a substance such as
   hide glue is used as a sizing, applied to the clean white
   braintanned hide before the paint is applied, or
   before it is smoked to leave a white area on the hide.
   Paint it on the areas or lines that you want to
   remain white, and let it dry. Then smoke the hide
   and the other blank areas will turn darker but the
   hide-glue-painted portions will not. This technique
   was used on painted Buffalo Robes.

 

     Some common binders that were used historically by
   Native Americans include human spit, hide glue, bone
   marrow fat, other animal fats such as bear grease,
   prickly pear cactus juice (may leave a green residue
   or tint), and soapy juice from yucca roots or leaves.
   California Indians also used a local plat called
   soaproot (Chlorogalum pomeridianum). Egg whites
   were used (bird eggs), milkweed (Asclepias sp.) sap
   and other plant saps, also urine.

 

     If the pigment is clay based, then the only thing that
   would need to be done is to add water to the processed
   pigment to make it stick together. If the pigment is
   pure mineral, then a small amount of glue should
   be added to the water to help it hold its desired shape.
   A thin mixture of hide glue works well. Hide glue,
   which is also known as rabbit skin glue or horse
   hoof glue, was traditionally made from cooking down
   all of the left over parts after an animal was butchered.
   Skin, bones, tendons etc. were cooked until they were
   reduced to basically solids, fats and gelatin. It is the
   gelatin that makes the glue.

 

     When choosing a binder, the questions you have
   to ask yourself are:
   What is the material that you are applying
   the pigment onto?
   How long do you want it to last?
   Will it need to be waterproof or at least water-resistant?
   Answers to all these questions determine the binder
   that will be used. The basic rule of thumb for applying
   pigments onto any surface is: the binder should be as
   similar a material you can find as the material to which
   you are applying it. Plant based oils, juices and saps
   should be used on woods and plant fibers; animal
   based oils, fats, egg yolks, eye and hide glues on
   hides, skins and bones. Experience using hide glue
   and milkweed sap as a binder has shown them to be
   water resistant on a variety of surfaces. Binders are
   as varied as the cultures that used them. Local
   materials would have been known and used.

 

     There are several differnt application methods that
   may be used, with or without a binder. Brushing the
   powdered dry pigment directly into the leather with
   the fingers is one way. Moss or fur can be used to
   daub and blend. A pointed stick or bone also works
   quite well for drawing lines. Using different kinds of
   primitive brushes to apply it is another way. Brushes
   were made of cut animal bones, hollow bones with
   animal hair inserted in the end, yucca fibers bound
   with cordage, feathers (trimmed or untrimmed), and
   dried yucca 


                 
 Below are pictures of some types of primitive  
                                                  brushes  
 
         

 

     Many of the beautiful rock images found in the
   European caves as well as the myriad of hand stencils
   from around the world were made by spraying the
   pigment out of the artists' mouth, sometimes through
   a tube. Any hollow tube of approximately .25 inch
   (6cm) diameter will work; bird or animal bones,
   bamboo, reeds etc. You can also blow the pigment
   out of your mouth without using a tube.  Although
   this technique may not be as controllable, the 
   Australian Aboriginal people still use this method
   today. 
   (Caution! When spaying any pigment out of your
   mouth, make sure binder does not contain any
   harmful materials, i.e.: poisonous or toxic plant
   saps, juice, etc.).

 

   ________________________________________________

          An Experiment in Rock Art 
                      Painting

     At the SHUMLA School in Comstock, Texas,
   archaeologist who were studying the 4000-year-old
   rock art in Seminole Canyon State Park did some
   experiments to try and replicate the paints used in
   the rock art. They found sources for the colors used
   in mineral deposits near the park, and obtained the
   pigments there. The pigments were ground to a
   fine powder using stone tools such as a mano and
   metate (flat grinding stones), or a molcajete
   (mortar and pestie).

 

     The next important ingredient in producing paint is
   the "binder". A binnder is the liquid in paints that
   holds particles of pigment together and fastens them
   to the support (in this case the support is the shelter
   wall). 

     Chemistry professor, Dr. Marvin Rowe, and his
   students at Texas A&M, determined that the binder
   used in the paint was of an organic nature, however;
   they still  did not know what kind of organic binder
   was used. In an attempt to answer this question,
   artist and archeologist Dr. Carolyn Boyd began the
   process of trying to rediscover the binder used 4000
   years ago through experimental archeology.

 

     Native Americans are reported to have used a variety
   of substances as binders in making paint, including
   blood, egg whites, sap from plants, animal fat and
   even urine. 

   As an artist well experienced in mural painting both
   indoors and outdoors, Boyd knew that the binder
   required to produce fluid continuous lines in an
   arid environment needed to be a slow drying
   substance. This eliminated such possible binders as
   blood, urine and egg whites. The binder also should
   be close to colorless when used to make such colors
   as yellows and whites, which again rules out blood.
   Quanity was also a consideration. The amount of
   binder required to produce some of the pictographs
   would be sizeable. Given these considerations, she
   determined that animal fat seemed the most likely
   source. In considering the fauna available 4000 years
   ago, Deer would have been an excellent source of fat.
   Dr. Boyd communicated with Dr. Jerry Cook, a
   wildlife ecologist at Texas A&M, and was informed
   that the highest source of fat on a deer is contained
   within the bone marrow, especially in the long bones
   of the tibia and radius, too red in the humerous
   and femur. She noted that the quanity and color of the
   marrow varied according to age, season, and health
   of the deer. The finely ground mineral pigments and
   the deer bone marrow blended easily, however, the
   consistency was too thick to be used for painting.
   A "thinner" was required to acheive the necessary
   fluidity.

 

     Water could not serve as the thinner due to its
   immiscibility or inability to mix with fat. Boyd needed
   a third ingredient that would act as an emulsifying
   agent to allow the water and the fat to be dispersed
   one into the other. She asked Dr. Phil Dering, a
   botonist and archeologist at Texas A&M, if there was
   a plant that could provide the needed emulsifier.
   He informed her that yucca, also known as soap
   plant, contains an ingredient known as saponin.
   Saponins are molecules that act like a detergent and
   are composed of a steroid attached to a sugar
   molecule. In aqueous solutions, sapponins have an
   ability to foam, thereby acting as an emulsifier. In
   reviewing the ethnographic literature, she found that
   yucca was not only used by various Native American
   groups as a detergent, but as a binder in paint as well.

 

     The roots of the yucca contain the most saponin.
   After removing the woody bark, Boyd pounded the
   roots enough to break them open and allowed them
   to soak in a small amount of water over night. The
   next day the roots were pounded into a pulpy mass
   and squeezed to render a soapy liquid.

 

     The yucca juice, combined with the water added in
   the processing of the yucca, served as an excellent
   emulsifier-thinner.
 The liquid mixed well with the fat
   and pigment, creating a silky, fluid paint. The
   consistency of the paint could be adjusted with
   varying quantities of yucca juice. The proportions
   needed of each ingredient varied depending on
   which mineral pigment was used, the quality of fat,
   and the concentration of yucca juice.

 

     The final product produced intense earth colors.
   The paint was highly fluid and easy to work with as
   commercial oil paints. The deer bone marrow served
   as an excellent binder when used in combination
   with yucca juice as the emulsifier-thinner. Although
   we do not know for certain that this combination
   of ingredients was the formula used by the ancient
   artists, we do not know that the formula works and
   the resources to create the paint would have been
   readily available to the atrists 4000 years ago in the
   lower Pecos River region of Texas.

 

    

 

_______________________________________________  

                     Using Natural Animal
                     Hide Glue

 

    (http://www.nativewayonline.com/glueinst.htm)

     Use a premium quality hide glue formulated to be
   water soluable and usable at different thicknesses.

    To Mix:
  
Prepare a pan that is clean and can take some heat.

    Mix approximately 50% by volume glue and water.
   Allow the glue to absorb the water completely.

    Apply heat to thoroughly mix and liquefy. Add more
   water as needed to bring the glue to the proper
   consistency. Most people try to use glue that is too
   thick. If you add too much water, either add more
   glue or cook the extra water out of the mix.

    Do  not scorch or boil the glue mix, as this can hurt
   the properties of the glue and cause objectionable
   odors.

 

   To Use:
   
Keep the workplace clean and free of excess glue by 
   careful application and quickly wiping spills with a
   wet cloth.

    Hide glue is liquid when hot or very warm and will
   gel or thicken if allowed to become cold. Do not
   hesitate to add more water or change the
   temperature of the glue to make it more usable.
   After the final application layer, use a warm, wet
   finger to smooth the surface of the glue and even
   out lumps or thin spots.

   Set piece aside and allow 10 to 24 hours for glue to dry
   completely before using.

    Natural hide glue will become sticky if exposed to
   excessive moisture, but must be soaked for hours before
   it will soften enough to lose it grip.

    Hide glue can be sanded smooth after drying, but pains
   should be taken to do the best job possible during the
   wet stages.

    Natural hide glue is compatible with natural sinews, gut
   hafting material, rawhide and leather. It will adhere to
   these materials and make a very strong, fiber reinforced
   bond. It is not compatible with waxed artificial sinew,
   nylon or other water resistant materials.

 

__________________________________________________

 

     Native Americans used many different "canvases"
   as places to apply pigment. Cave walls and rocks
   have already been discussed. Here are some more
   places where pigment was and is applied.

 

    Natural pigments paints are a traditional source of
   color among Native Americans for face and body
   paint on humans and horses as well as paintings on
   rawhide and finished hides. These guidelines describe
   some techniques for application.

 

   Face and Body:

   For the face and body, the paint can be mixed with
   bear grease into a thick, rich color. Mix with pigment
   for desired color. Apply with fingertips. Solid areas
   of color can be etched to create a pattern.

 

   Animals:

   Horses were often decorated with paints to signify
   ownership and battle honors. Paint can be mixed
   very thickly with water and painted with the hands
   and fingers since larger designs are desired. Paint can
   also be mixed with grease for this purpose, although
   will be harder to remove from the hair.

 

   Rawhide:

   Rawhide articles such as parfleche were painted
   while still damp in order for the pigment to penetrate
   and mix with the natural glues in the hide. We have
   created instructions for painting rawhide dry using
   our hide glue to produce a similar result. "Brushes"
   of varying widths were generally made from porous
   bone or willow sticks which soaked the paint into
   them. The paint could then be worked into the fibers.
   After drying, a protective coating (called sizing) was
   applied to the surface to protect it. Native Americans
   often used the juice of Cactus for this purpose.

 

   Hides or Cloth:

   Pigment paints can be used for intricate designs, and
   for coloring larger areas on hides and cloth. To stain
   a large area, use the pigments dry and apply by
   dipping a piece of buckskin or similar material into
   the powder and rubbing it onto the surface until the
   desired effect is acheived. When rubbing paint in dry
   form, shake off any excess outdoors, then use a clean
   applicator to continue to rub off or "transfer".  To
   make an authentic, colorfast liquid paint for hides,
   pigments can be mixed with water and hide glue.

 

   For authnetic use and style of application of natural
   pigments to clothing and accessories, you need to
   study plenty of artifacts to get a feel for design and
   color. Here is a treasure trove online of Native
   American artifacts from the Natural Museum
   Collection:

      http://anthro.amnh.org/anthropology/databases/northpublic/northpublic.htm

   It allows you to search by tribe, region or object name
   to view photographs of items of evreyday living from
   clothing to utensils, etc. There you will find several
   examples of earth paint on parfleche, other rawhide
   and hide items, shirts, moccasins and clothing to
   inspire and teach you.

_________________________________________

 

     Dr. Solveig A. Turpin is a recognized authority on
   the rock of the lower Pecos Region, with a P.H.D. in
   anthropology from the University of Texas. She has
   unique insights into the hunter-gather lifeways of
   the lower Pecos people and the probable shamanic
   origins of these rock art paintings. From the rock
   art foundation website, she comments on the
   probable spiritual significance of color in those
   ancient times: "The dominant color used in the
   paintings, no matter their age or subject material,
   is red. This is true in all the styles, from the earliest
   Pecos River shamans to the latest historic
   autobiography. The names given to two of the
   styles-Red Linear and Red Monochrome-attest to
   this overwhelming popularity. Some of the selectivity
   can be attributed to obvious factors-such as
   availablity and durability; other factors are more
   esoteric and aesthetic...the first response that leaps
   to mind when asked about the color red is blood,
   the essential fluid that courses through the veins of
   all humans and animals. Of course, early people
   were aware that loss of blood meant loss of life,
   but they also knew that new life arrives in blood
   as well...Psychologist and linguists studying people
   who still live at a very elemental technological and
   social level have found that the first colors to be
   distinguished (i.e., named) are black, white, and
   red. These we could call 'all color', 'no color', and
   red. The strongest impulse on the chromatic wave
   length is red so we are in a sense hard-wired to react
   to red before any other color...To me, it is not merely
   a coincidence that the most sophisticated art-and
   the most clearly rooted in a ritual context-uses more
   than one color...we can envision the Pecos River
   and Bold Line Geometric styles as developing
   within a trance-oriented religion, where multi-colored
   visions are expectable".

 

     Color is the most basic form of human artistic
   expression, and pigments are the simplest forms of
   color-in essence, they are all reflections of light.
   Since these ancient artists are long gone from this
   world, we may never know  the true spiritual
   significance of the colors in their rock art. But we
   can see how deeply color affects our own mood,
   our self-esteem, and our sense of beauty; and how
   it touches our soul. And we can take care to learn
   these ancient methods and traditions and preserve
   them for generations to come, after we are long gone
   as well.

                                               Patsy Harper                              

 

_______________________________________  
   Reference

   1) Pigments through the ages-how artists have colored our lives-      
        http://webexhibits.org/pigments/   

    2) Rock Art Foundation, Seminole Canyon rock art-color significance
       
 http://www.rockart.org/faq/2000 02.htm

    3) Paint-Making in Prehistory
        http://www.shumla.org/discover/paintmaking.htm   

    4) Tom Haukaas, museum curator from Europe, e-mail to Plains
        Indian Seminar Yahoo group.

    5) Use of Oak galls for black dye and polypores for blue dye,
        other pigments: Kimberly Packwood on pigments and dyeing,
        e-mail conversation, April,2005-Native Ameerican Skills
        Technology Yahoo group.

    6) Peter Bowles, e-mail conversation on the Plains Indian Seminar
        Yahoo group list, Sept.,2005

    7) Kiowa artifacts from the National Museum of American History,
        photographed by Paul Calcaterra, posted by e-mail to the Plains
        Indian Seminar Yahoo group list, Sept.,2005

    8) Jack Smith, e-mail conversation and photos posted to the Plains
        Indian Seminar Yahoo group, Sept.,2005

    9) Patsy Harper, independant research

    10) Allen Chronister, artifact collector and author, e-mail
          conversation 12/15/04 on the Plains Indian Seminar Yahoo
          group.

    11) Kathy and Bill Brewer, nationally recognized creators of
          reproductions of Native Ammerican artifacts for collectors,
          movies, and museums, e-mail conversation on the Plains
          Indian Seminar yahoo group-Sept.,2005

    12) Using Natural Animal Hide Glue for primitive weaponry projects:
          
 http://www.nativewayonline.com/glues.htm

    13) Primitive Ways article: "How to Paint a Mammoth", by Chuck
          Krizon, published in The Bulletin of     Primitive Technology.
         (Fall 2002, #24)
         http://www.primitiveways.com/paint a mammoth.html
         
 

    14) Rick Hamilton, ethnobotanist, primitive skills instructor,
          e-mail conversation on the Native American Skills
         Technology yahoo group.

    15) Using Painted Cliffs Earth and Mineral Pigments:
    
http://www.nativeamericanvisions.com/catalog/index.cfm?subCat id=36

     http://www.nativeamericanvisions.com/content.cfm?id=22


    16) Symbolism to this artist Lorena Moore ("Ironwing"), of earth
          pigments, and sources for them

     http://mineralarts.com/artwwork/paintedEarth.html

 
    17) Tara Prindle, e-mail to the Native American Skills
          Technology Yahoo group

    18) Gary Winder, e-mail to the Lodge Owners Yahoo group

    19) "Art and writing on the Frontier", by Cathy Johnson in 
           Muzzleloader Magazine's "The Book Of Buckskinning
          VII".

 

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